As this was already the second time i faced the "Unable to install bootstrap, bootstrap.settings already exists in active configuration." problem i decided to share a quick and simple solution.
Background: I have faced this error when performing the Drupal 7 upgrade to the Drupal 9 version and trying to enable the bootstrap theme.
solution: in PHPMyAdmin open the database your Drupal site is running, in the Search tab enter "bootstrap"
Make sure you select all under tables and click the go button
You will get a result with rows showwin where bootstrap setting might belocated, in our case, table config
Simply click the delete on config.
that's it - now you should be able to install and activate the bootstrap theme for Drupal